Preprints
Publications
Energy Spotlight: Electrochemical Ethylene Oxide Synthesis from Ethanol
Lovell, E. C.; Ager, J. W.; Kim, Y. S.; Modestino, M. A. (2022) Energy Spotlight. ACS Energy Letters. Chemically-informed data-driven optimization (ChIDDO): leveraging physical models and Bayesian learning to accelerate chemical research
Frey, D., Shin, J., Musco, C., & Modestino, M. A. (2022). Chemically-informed data-driven optimization (ChIDDO): Leveraging physical models and Bayesian learning to accelerate chemical research. Reaction Chemistry & Engineering.
A compact electron transport layer using a heated tin-oxide colloidal solution for efficient perovskite solar cells
Meng, J., Röhr, J.A., Wang, H., Edward Sartor, B., Song, D., Katzenberg, A., Modestino, M.A., Xu, Z., Kong, J. and Taylor, A.D. (2021), A compact electron transport layer using a heated tin-oxide colloidal solution for efficient perovskite solar cells. Sol. RRL. Accepted Author Manuscript.
CO2 doping of organic interlayers for perovskite solar cells
Jaemin Kong, Yongwoo Shin, Jason A. Röhr, Hang Wang, Juan Meng, Yueshen Wu, Adlai Katzenberg, Geunjin Kim, Dong Young Kim, Tai-De Li, Edward Chau, Francisco Antonio, Tana Siboonruang, Sooncheol Kwon, Kwanghee Lee, Jin Ryoun Kim, Miguel A. Modestino, Hailiang Wang & André D. Taylor. CO2 doping of organic interlayers for perovskite solar cells. Nature 594, 51–56 (2021).
Engineering an Interdisciplinary Connection: Bridging Gaps between Chemical, Electrical, and Environmental Engineers
Dvorkin, Yury, Miguel A. Modestino, and Andrea I. Silverman. "Engineering an Interdisciplinary Connection: Bridging Gaps between Chemical, Electrical, and Environmental Engineers." Iscience 23.7 (2020).
Spatiotemporal Decoupling of Water Electrolysis for Dual-Use Grid Energy Storage and Hydrogen Generation
Frey, D.; Kim, J.; Dvorkin, Y.; Modestino, M. A., Spatiotemporal Decoupling of Water Electrolysis for Dual-Use Grid Energy Storage and Hydrogen Generation. Cell Reports Physical Science. 2020, 1 (10)
Electro-organic Syntheses for Green Chemical Manufacturing
Biddinger, Elizabeth J., and Miguel A. Modestino. "Electro-organic Syntheses for Green Chemical Manufacturing." Electrochemical Society Interface (2020).
Controlling Selectivity in the Electrocatalytic Hydrogenation of Adiponitrile through Electrolyte Design
Blanco, D. E., Dookith, A. Z., Modestino, M. A. (2020). "Controlling Selectivity in the Electrocatalytic Hydrogenation of Adiponitrile through Electrolyte Design." ACS Sustainable Chemistry & Engineering.
Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors
Angulo, A., van der Linde, P., Gardeniers, H., Modestino, M., & Fernández Rivas, D. (2020). Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors. Joule.
Photocatalytic Hydrogels for Removal of Organic Contaminants from Aqueous Solution
Katzenberg, A., Raman, A., Schnabel, N. L., Quispe, A. L., Silverman, A. I., & Modestino, M. A. (2020). Photocatalytic hydrogels for removal of organic contaminants from aqueous solution in continuous flow reactors. Reaction Chemistry & Engineering.
Practical Challenges in the Development of Photoelectrochemical Solar Fuels Production
Spitler, M. T., Modestino, M. A., Deutsch, T. G., Xiang, C. X., Durrant, J. R., Esposito, D. V., ... & Ginley, D. S. (2020). Practical challenges in the development of photoelectrochemical solar fuels production. Sustainable Energy & Fuels.
Decoupling Gas Evolution from Water-Splitting Electrodes
Peñas, P., van der Linde, P., Vijselaar, W., van der Meer, D., Lohse, D., Huskens, J., ... & Rivas, D. F. (2019). Decoupling gas evolution from water-splitting electrodes. Journal of The Electrochemical Society, 166(15), H769-H776. Organic Electrosynthesis through Controlled Voltage Dosing and Artificial Intelligence
Blanco, D. E., Lee, B., & Modestino, M. A. (2019). Optimizing organic electrosynthesis through controlled voltage dosing and artificial intelligence. Proceedings of the National Academy of Sciences, 116(36), 17683-17689. A comparative performance analysis of stand-alone, off-grid solar-powered sodium hypochlorite generators
Chinello, E., Modestino, M. A., Schüttauf, J. W., Coulot, L., Ackermann, M., Gerlich, F., ... & Moser, C. (2019). A comparative performance analysis of stand-alone, off-grid solar-powered sodium hypochlorite generators. RSC advances, 9(25), 14432-14442.
Enhancing Selectivity and Efficiency in the Electrochemical Synthesis of Adiponitrile
Blanco, D. E., Dookhith, A. Z., & Modestino, M. A. (2019). Enhancing selectivity and efficiency in the electrochemical synthesis of adiponitrile. Reaction Chemistry & Engineering, 4(1), 8-16.
Pathways to electrochemical solar-hydrogen technologies
Ardo, S., Rivas, D. F., Modestino, M. A., Greiving, V. S., Abdi, F. F., Llado, E. A., ... & Bederak, D. (2018). Pathways to electrochemical solar-hydrogen technologies. Energy & environmental science, 11(10), 2768-2783.
A 25.1% Efficient Stand-Alone Solar Chloralkali Generator Employing a Microtracking Solar Concentrator
Chinello, E., Modestino, M. A., Coulot, L., Ackermann, M., Gerlich, F., Psaltis, D., & Moser, C. (2017). A 25.1% Efficient Stand‐Alone Solar Chloralkali Generator Employing a Microtracking Solar Concentrator. Global Challenges, 1(9), 1700095.
Solar-to-Hydrogen Production at 14.2% Efficiency with Silicon Photovoltaics and Earth-Abundant Electrocatalysts
Jan-Willem Schüttauf, Miguel A. Modestino, Enrico Chinello, David Lambelet, Antonio Delfino, Didier Dominé, Antonin Faes, Matthieu Despeisse, Julien Bailat, Demetri Psaltis, Christophe Moser and Christophe Ballif. J. Electrochem. Soc., 2016, 163, 10, F1177-F1181
The potential for microfluidics in electrochemical energy systems
Miguel A Modestino, D Fernandez Rivas, Seyyed Mohammad Hosseini Hashemi, JGE Gardeniers, Demetri Psaltis. Energy and Environmental Science, 2016, 9, 3381-3391
Modeling, Simulation, and Implementation of Solar-Driven Water-Splitting Devices
Chengxiang Xiang, Adam Z. Weber, Shane Ardo, Alan Berger, YiKai Chen, Robert Coridan, Katherine T. Fountaine, Sophia Haussener, Shu Hu, Rui Liu, Nathan S. Lewis, Miguel A. Modestino, Matthew M. Shaner, Meenesh R. Singh, John C. Stevens, Dr. Ke Sun, Karl Walczak. Angew. Chem. Int. Ed. 2016, 55; DOI: 10.1002/anie.201510463
Inkjet printing of viscous monodisperse microdroplets by
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Machine Learning Enhanced Spectroscopic Analysis: Towards Autonomous Chemical Mixture Characterization for Rapid Process Optimization
Angulo, A., Yang, L., Aydil, E. S., & Modestino, M. A. (2022). Machine Learning Enhanced Spectroscopic Analysis: Towards Autonomous Chemical Mixture Characterization for Rapid Process Optimization. Digital Discovery.
Electrocatalytic hydrogenation of nitriles: A step toward electrification of amine production
Mathison, Ricardo; Modestino, Miguel A. "Electrocatalytic hydrogenation of nitriles: A step toward electrification of amine production". Chem Catalysis (2021).
Impacts of Organic Sorbates on the Ionic Conductivity and Nanostructure of Perfluorinated Sulfonic-Acid Ionomers
Katzenberg, Adlai; Angulo, Andrea; Kusoglu, Ahmet; Modestino, Miguel. "Impacts of Organic Sorbates on the Ionic Conductivity and Nanostructure of Perfluorinated Sulfonic-Acid Ionomers." Macromolecules (2021).
Effect of Electrolyte Cations on Organic Electrosynthesis: the Case of Adiponitrile Electrochemical Production
Blanco, D. E., Atwi, R., Sethuraman, S., Lasri, A., Morales, J., Rajput, N. N., & Modestino, M. A. (2020). Effect of Electrolyte Cations on Organic Electrosynthesis: the Case of Adiponitrile Electrochemical Production. Journal of the Electrochemical Society.
Dynamic Emergence of Nanostructure and Transport Properties in Perfluorinated Sulfonic Acid Ionomers
Katzenberg, A.; Mukherjee, D.; Dudenas, P. J.; Okamoto, Y.; Kusoglu, A.; Modestino, M. A., Dynamic Emergence of Nanostructure and Transport Properties in Perfluorinated Sulfonic Acid Ionomers. Macromolecules 2020.
Acid-Doped Hydrogel Electrolytes for Electrocatalyst Interfaces
Katzenberg, A., Muñoz Davila, C., Chen, B., Siboonruang, T., & Modestino, M. A. (2020). Acid-Doped Hydrogel Electrolytes for Electrocatalyst Interfaces. ACS Applied Polymer Materials. Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure-Property Relationships
Katzenberg, A., Chowdhury, A., Fang, M., Weber, A. Z., Okamoto, Y., Kusoglu, A., & Modestino, M. A. (2020). Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure–Property Relationships. Journal of the American Chemical Society. Insights into membrane-separated organic electrosynthesis: the case of adiponitrile electrochemical production
Blanco, D. E., Prasad, P. A., Dunningan, K., & Modestino, M. A. (2020). Insights into membrane-separated organic electrosynthesis: the case of adiponitrile electrochemical production. Reaction Chemistry & Engineering, 5(1), 136-144. Quantum confinement in few layer SnS nanosheets
Dwyer, J. D., Diaz, E. J., Webber, T. E., Katzenberg, A., Modestino, M. A., & Aydil, E. S. (2019). Quantum confinement in few layer SnS nanosheets. Nanotechnology, 30(24), 245705.
Organic Electrosynthesis for Sustainable Chemical Manufacturing
Blanco, D. E., & Modestino, M. A. (2019). Organic electrosynthesis for sustainable chemical manufacturing. Trends in Chemistry, 1(1), 8-10.
Inertial manipulation of bubbles in rectangular microfluidic channels
Hadikhani, P., Hashemi, S. M. H., Balestra, G., Zhu, L., Modestino, M. A., Gallaire, F., & Psaltis, D. (2018). Inertial manipulation of bubbles in rectangular microfluidic channels. Lab on a Chip, 18(7), 1035-1046.
Membrane-less micro fuel cell based on two-phase flow
S.M.H. Hashemi , M. Neuenschwander, P. Hadikhani, M.A. Modestino, D. Psaltis. Journal of Power Sources 348, 2017 212-218 Mass transport aspects of electrochemical solar-hydrogen generation
Miguel A. Modestino, SM Hosseini Hashemi, Sophia Haussener, Energy and Environmental Science, 2016, 9, 1533-1551
Hollow mesoporous plasmonic nanoshells for enhanced solar vapor generation
Marcin S. Zielinski, Jae-Woo Choi, Thomas La Grange, Miguel A. Modestino, Seyyed Mohammad Hosseini Hashemi, Ye Pu, Susanne Birkhold, Jeffrey A. Hubbell, and Demetri Psaltis, Nano Lett., 2016, 16 (4), pp 2159–2167
A membrane-less electrolyzer for hydrogen production across the pH scale
S. Mohammad H. Hashemi, Miguel A. Modestino, Demetri Psaltis Energy Environ. Sci., 2015, 8, 2003-2009
Enhanced Water Vapor Blocking in Transparent Hybrid Polymer–Nanocrystal Films
Eun Seon Cho, Christopher M Evans, Emily C Davidson, Megan L Hoarfrost, Miguel A Modestino, Rachel A Segalman, Jeffrey J Urban, ACS Macro Lett., 2015, 4 (1), pp 70–74
Morphology of Hydrated As-Cast Nafion Revealed through Cryo Electron Tomography
Frances I Allen, Luis R Comolli, Ahmet Kusoglu, Miguel A Modestino, Andrew M Minor, Adam Z Weber. ACS Macro Letters 4, 1-5, 2015
High Anion Conductivity and Low Water Uptake of Phosphonium Containing Diblock Copolymer Membranes
Pepa Cotanda, Guillaume Sudre, Miguel A. Modestino, X. Chelsea Chen, Nitash Balsara, Macromolecules, 2014, 47 (21), pp 7540–7547
Integrated microfluidic test-bed for energy conversion devices
Miguel A. Modestino, Camilo
Diaz-Botia, Tyler S. Matthews, Rafael Gomez-Sjoberg, Joel Ager, Rachel A.
Segalman. Phys. Chem. Chem. Phys. 2013, 15, 7050-7054
Self-assembly and transport limitations in confined Nafion films
Miguel A. Modestino, Frances I. Allen, Devproshad K. Paul, Shudipto Dishari, Stephanie A. Petrina, Michael A. Hickner, Kunal Karan, Andy M. Minor, Adam Z. Weber and Rachel A. Segalman. Macromolecules, 2013, 46 (3), pp 867–873
Ionic Conduction in Nanostructured Membranes based on Protic Ionic Liquids
Yanika Schneider, Miguel A. Modestino, Robert W. Hess, Bryan McCulloch, Rachel A. Segalman. Macromolecules, 2013, 46 (4), pp 1543–1548.
Subsecond Morphological Changes in Nafion during Water Uptake Detected by Small-Angle X-ray Scattering
Ahmet Kusoglu, Miguel A. Modestino, Alexander Hexemer, Adam Z. Weber, Rachel A. Segalman. ACS Macro Lett.; 2012; 1 (1), pp 33–36.
Factors Influencing the Interdiffusion of Weak Polycations in Multilayers
Nicole S. Zacharia, Miguel Modestino, and Paula T. Hammond
Macromolecules, 2007, 40 (26), pp 9523–9528 Controlling Diffusion and Exchange in Layer-by-Layer AssembliesNicole S. Zacharia, Dean M. DeLongchamp, Miguel Modestino, and Paula T. Hammond
Macromolecules, 2007, 40 (5), pp 1598–1603 Controlling Nanorod Self-Assembly in Polymer Thin Films
M. A. Modestino, E. R. Chan, A. Hexemer, J.J. Urban, and R.A. Segalman. Macromolecules, 2011, 44 (18), pp 7364–7371
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