Publications

Preprints

Impacts of Organic Sorbates on Ionic Conductivity and Nanostructure of Perfluorinated Sulfonic-Acid Ionomers

Katzenberg, Adlai; Angulo, Andrea; Kusoglu, Ahmet; Modestino, Miguel (2021): Impacts of Organic Sorbates on Ionic Conductivity and Nanostructure of Perfluorinated Sulfonic-Acid Ionomers. ChemRxiv. Preprint.

Publications

Engineering an Interdisciplinary Connection: Bridging Gaps between Chemical, Electrical, and Environmental Engineers

Dvorkin, Yury, Miguel A. Modestino, and Andrea I. Silverman. "Engineering an Interdisciplinary Connection: Bridging Gaps between Chemical, Electrical, and Environmental Engineers." Iscience 23.7 (2020).

Spatiotemporal Decoupling of Water Electrolysis for Dual-Use Grid Energy Storage and Hydrogen Generation

Frey, D.; Kim, J.; Dvorkin, Y.; Modestino, M. A., Spatiotemporal Decoupling of Water Electrolysis for Dual-Use Grid Energy Storage and Hydrogen Generation. Cell Reports Physical Science. 2020, 1 (10)

Electro-organic Syntheses for Green Chemical Manufacturing

Biddinger, Elizabeth J., and Miguel A. Modestino. "Electro-organic Syntheses for Green Chemical Manufacturing." Electrochemical Society Interface (2020).

Controlling Selectivity in the Electrocatalytic Hydrogenation of Adiponitrile through Electrolyte Design

Blanco, D. E., Dookith, A. Z., Modestino, M. A. (2020). "Controlling Selectivity in the Electrocatalytic Hydrogenation of Adiponitrile through Electrolyte Design." ACS Sustainable Chemistry & Engineering.

Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors

Angulo, A., van der Linde, P., Gardeniers, H., Modestino, M., & Fernández Rivas, D. (2020). Influence of Bubbles on the Energy Conversion Efficiency of Electrochemical Reactors. Joule.

Photocatalytic Hydrogels for Removal of Organic Contaminants from Aqueous Solution

Katzenberg, A., Raman, A., Schnabel, N. L., Quispe, A. L., Silverman, A. I., & Modestino, M. A. (2020). Photocatalytic hydrogels for removal of organic contaminants from aqueous solution in continuous flow reactors. Reaction Chemistry & Engineering.

Practical Challenges in the Development of Photoelectrochemical Solar Fuels Production

Spitler, M. T., Modestino, M. A., Deutsch, T. G., Xiang, C. X., Durrant, J. R., Esposito, D. V., ... & Ginley, D. S. (2020). Practical challenges in the development of photoelectrochemical solar fuels production. Sustainable Energy & Fuels.

Decoupling Gas Evolution from Water-Splitting Electrodes

Peñas, P., van der Linde, P., Vijselaar, W., van der Meer, D., Lohse, D., Huskens, J., ... & Rivas, D. F. (2019). Decoupling gas evolution from water-splitting electrodes. Journal of The Electrochemical Society, 166(15), H769-H776.

Organic Electrosynthesis through Controlled Voltage Dosing and Artificial Intelligence

Blanco, D. E., Lee, B., & Modestino, M. A. (2019). Optimizing organic electrosynthesis through controlled voltage dosing and artificial intelligence. Proceedings of the National Academy of Sciences, 116(36), 17683-17689.

A comparative performance analysis of stand-alone, off-grid solar-powered sodium hypochlorite generators

Chinello, E., Modestino, M. A., Schüttauf, J. W., Coulot, L., Ackermann, M., Gerlich, F., ... & Moser, C. (2019). A comparative performance analysis of stand-alone, off-grid solar-powered sodium hypochlorite generators. RSC advances, 9(25), 14432-14442.

Enhancing Selectivity and Efficiency in the Electrochemical Synthesis of Adiponitrile

Blanco, D. E., Dookhith, A. Z., & Modestino, M. A. (2019). Enhancing selectivity and efficiency in the electrochemical synthesis of adiponitrile. Reaction Chemistry & Engineering, 4(1), 8-16.

Pathways to electrochemical solar-hydrogen technologies

Ardo, S., Rivas, D. F., Modestino, M. A., Greiving, V. S., Abdi, F. F., Llado, E. A., ... & Bederak, D. (2018). Pathways to electrochemical solar-hydrogen technologies. Energy & environmental science, 11(10), 2768-2783.

A 25.1% Efficient Stand-Alone Solar Chloralkali Generator Employing a Microtracking Solar Concentrator

Chinello, E., Modestino, M. A., Coulot, L., Ackermann, M., Gerlich, F., Psaltis, D., & Moser, C. (2017). A 25.1% Efficient Stand‐Alone Solar Chloralkali Generator Employing a Microtracking Solar Concentrator. Global Challenges, 1(9), 1700095.

Solar-to-Hydrogen Production at 14.2% Efficiency with Silicon Photovoltaics and Earth-Abundant Electrocatalysts

Jan-Willem Schüttauf, Miguel A. Modestino, Enrico Chinello, David Lambelet, Antonio Delfino, Didier Dominé, Antonin Faes, Matthieu Despeisse, Julien Bailat, Demetri Psaltis, Christophe Moser and Christophe Ballif. J. Electrochem. Soc., 2016, 163, 10, F1177-F1181

The potential for microfluidics in electrochemical energy systems

Miguel A Modestino, D Fernandez Rivas, Seyyed Mohammad Hosseini Hashemi, JGE Gardeniers, Demetri Psaltis. Energy and Environmental Science, 2016, 9, 3381-3391

Modeling, Simulation, and Implementation of Solar-Driven Water-Splitting Devices

Chengxiang Xiang, Adam Z. Weber, Shane Ardo, Alan Berger, YiKai Chen, Robert Coridan, Katherine T. Fountaine, Sophia Haussener, Shu Hu, Rui Liu, Nathan S. Lewis, Miguel A. Modestino, Matthew M. Shaner, Meenesh R. Singh, John C. Stevens, Dr. Ke Sun, Karl Walczak. Angew. Chem. Int. Ed. 2016, 55; DOI: 10.1002/anie.201510463

Inkjet printing of viscous monodisperse microdroplets by
laser-induced flow focusing

Delrot P., Modestino A. M., Gallaire F., Psaltis D., Moser C. Phys. Rev. Applied 6, 024003, 2016.

Vapor-fed microfluidic hydrogen generator

Miguel A. Modestino, Mikaël Dumortier, SM Hosseini Hashemi, Sophia Haussener, Christophe Moser, Demetri Psaltis. Lab on a Chip, 2015, 15, 2287-2296

An Integrated Device View on Photoelectrochemical Solar-Hydrogen Generation

Miguel A. Modestino and Sophia Haussener, Annual Review of Chemical and Biomolecular Engineering 6 (1), 13-34, 2015

Design and cost considerations for practical solar-hydrogen generators

Claudia A. Rodriguez, Miguel A. Modestino, Demetri Psaltis and Christophe Moser. Energy Environ. Sci., 2014, 7, 3828-3835

Robust production of purified H2 in a stable, self-regulating, and continuously operating solar fuel generator

Miguel A. Modestino, Karl A. Walczak, Alan Berger, Christopher Evans, Sophia Haussener, Carl Koval, John S. Newman, Joel Ager, Rachel A. Segalman
Energy Environ. Sci., 2014, 7, 297-301

Artificial Solar Fuel Generators

Miguel A. Modestino, Rachel A. Segalman. The Brige, Frontiers of Engineering, Winter 2014, Vol. 43, Num. 4

Deciphering the Three-Dimensional Morphology of Block Copolymer Thin Films by Transmission Electron Microscopy

Frances I. Allen, Peter Ercius, Miguel A. Modestino, Rachel A. Segalman, Nitash P. Balsara, Andrew M. Minor. Micron; 2013; 44, pp 442-450.

Controlling Nafion Structure and Properties via Wetting Interactions

Miguel A. Modestino, Ahmet Kusoglu, Alexander Hexemer, Adam Z. Weber, and Rachel A. Segalman
Macromolecules, 2012; 45 (11), pp 4681–4688

Structure Determination of Pt-coated Au Dumbbells via Fluctuation X-ray Scattering.

Gang Chen, Miguel A. Modestino, Billy K. Poon, Andre Schrotzek, Stefano Marchesini, Rachel A. Segalman, Alexander Hexemer, Peter H. Zwart. Journal of Synchrotron Radiation; 2012; 19, pp 695-700.

Effect of Electrolyte Cations on Organic Electrosynthesis: the Case of Adiponitrile Electrochemical Production

Blanco, D. E., Atwi, R., Sethuraman, S., Lasri, A., Morales, J., Rajput, N. N., & Modestino, M. A. (2020). Effect of Electrolyte Cations on Organic Electrosynthesis: the Case of Adiponitrile Electrochemical Production. Journal of the Electrochemical Society.

Dynamic Emergence of Nanostructure and Transport Properties in Perfluorinated Sulfonic Acid Ionomers

Katzenberg, A.; Mukherjee, D.; Dudenas, P. J.; Okamoto, Y.; Kusoglu, A.; Modestino, M. A., Dynamic Emergence of Nanostructure and Transport Properties in Perfluorinated Sulfonic Acid Ionomers. Macromolecules 2020.

Acid-Doped Hydrogel Electrolytes for Electrocatalyst Interfaces

Katzenberg, A., Muñoz Davila, C., Chen, B., Siboonruang, T., & Modestino, M. A. (2020). Acid-Doped Hydrogel Electrolytes for Electrocatalyst Interfaces. ACS Applied Polymer Materials.

Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure-Property Relationships

Katzenberg, A., Chowdhury, A., Fang, M., Weber, A. Z., Okamoto, Y., Kusoglu, A., & Modestino, M. A. (2020). Highly Permeable Perfluorinated Sulfonic Acid Ionomers for Improved Electrochemical Devices: Insights into Structure–Property Relationships. Journal of the American Chemical Society.

Publications​

Preprints

Publications

Engineering an Interdisciplinary Connection: Bridging Gaps between Chemical, Electrical, and Environmental Engineers​​

Vapor-fed microfluidic hydrogen generator﻿

An Integrated Device View on Photoelectrochemical Solar-Hydrogen Generation﻿

﻿Robust production of purified H2 in a stable, self-regulating, and continuously operating solar fuel generator

﻿Artificial Solar Fuel Generators﻿

Effect of Electrolyte Cations on Organic Electrosynthesis: the Case of Adiponitrile Electrochemical Production​

Acid-Doped Hydrogel Electrolytes for Electrocatalyst Interfaces​

Mass transport aspects of electrochemical solar-hydrogen generation﻿

Enhanced Water Vapor Blocking in Transparent Hybrid Polymer–Nanocrystal Films﻿

High Anion Conductivity and Low Water Uptake of Phosphonium Containing Diblock Copolymer Membranes﻿

Publications

Engineering an Interdisciplinary Connection: Bridging Gaps between Chemical, Electrical, and Environmental Engineers

Vapor-fed microfluidic hydrogen generator

An Integrated Device View on Photoelectrochemical Solar-Hydrogen Generation

Robust production of purified H2 in a stable, self-regulating, and continuously operating solar fuel generator

Artificial Solar Fuel Generators

Effect of Electrolyte Cations on Organic Electrosynthesis: the Case of Adiponitrile Electrochemical Production

Acid-Doped Hydrogel Electrolytes for Electrocatalyst Interfaces

Mass transport aspects of electrochemical solar-hydrogen generation

Enhanced Water Vapor Blocking in Transparent Hybrid Polymer–Nanocrystal Films

High Anion Conductivity and Low Water Uptake of Phosphonium Containing Diblock Copolymer Membranes